Hydroamination of ferrocene-containing electrono-deficient alkenes and alkynes

Author: Avthandil Koridze
Co-authors: O.Lekashvili, N. Batiashvili
Keywords: aldoximes, amides, nitriles, rearrangement, alkenes, alkynes, hydroamination
Annotation:

The complexes RuCl2(dmso)4 and RhCl(PPh3)3 was found to be effective homogeneous catalysts for rearrangement of functionalized aldoximes into primary amides. Several ferrocene-containing amido and cyano alkenes and alkynes have been synthesized. These electron-deficient alkenes and alkynes will be used in hydroamination with primary, secondary amines and N-heterocycles.

Lecture files:

Hydroamination of ferrocene-containing electron-deficient alkenes and alkynes [en]
ფეროცენშემცველი ელექტრონოდეფიციტური ალკენების და ალკინების ჰიდროამინირება [ka]